At the time, Higher Sur is an overcome outpost and you can household out of Henry Miller as well as the screenwriter Dennis Murphy, every one of who Thompson acknowledged. During this time, he wrote 1st mag function in to the Rogue regarding your artisan and bohemian individuals of Large Sur and handled The newest Rum Log. He were able to publish you to definitely quick-tale, «Burial from the Water,» that also starred in Rogue.
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It appears the lattice airplanes (0.21 nm) from diamond derive from the newest graphite (002) flat from the lattice distortion. To have city cuatro (FT4), diamond lattice fringes (0.21 nm) get to be the fundamental lattice which have a virtually disappearance away from graphite (002) lattice fringes, proving you to definitely graphite entirely transits in order to diamond. While in the 150 to help you 210 s, the change inside the Raman spectra is much like regarding 31 to help you 90 s, confirming that periodic alter observed in the exterior morphology develop on the solution appearance of VGs and you may NCD. FESEM images for trials growing using (A) 0 s, (B) 31 s, (C) 60 s, (D) 90 s, (E) 120 s, (F) 150 s, (G) 180 s, and you may (H) 210 s inside 2nd growth procedure at the step one,800 W.
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It shows that regarding the H, O, and you may Ta complex surroundings of your CVD ecosystem, diamond is formed by phase conversion away from graphite. This also provides an angle to know the organization device out of information with sp2 and you will sp3 digital settings. X-beam photoelectron spectroscopy (XPS) (Fig. 4A and you will Si Appendix, Fig. S7) reveals obvious Ta and O feature intake peaks, the spot where the oxygen atoms is actually fused having carbon. Also, HAADF and energy dispersive spectrometry (EDS) mapping images (Fig. 4B) tell you atomically spread Ta atoms. This gives you desire to determine whether Ta atoms play a great trick part from the phase change.
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